Sunday, September 28, 2014

Calculating matrix exponentials.
 I wanted to calculate by hand the exponential of a 3x3 matrix so I wrote out examples of two methods of doing this. To see the PDF click on the link below.

https://drive.google.com/file/d/0BxPw8lRke1HBQnd2RzFkNVYtQjA/view?usp=sharing




The kinetics of consecutive reactions.
This post presents the kinetic equation for consecutive chemical reactions of the type:

with irreversible, first order steps. They have rate constants k1 and k2 s-1. Let the concentrations of the reactants be expressed as xt,  yt,  zt  where xt  is the concentration of x at time t.
The kinetics of the sequence are completely determined by the equation:

 This solution was derived using Williamson’s algorithm as described below
https://drive.google.com/file/d/0BxPw8lRke1HBdmpfQ2hNMFFfVVU/view?usp=sharing.



















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