Friday, November 28, 2014

Covariant and contravariant components, the metric tensor


This blog gives an elementary explanation of the terms covariant and contravariant as applied to vectors and describes how vectors transform under a change of coordinates. The notions of metric tensor and metric equation are explained.




Monday, November 3, 2014



The kinetics of three-stage, successive, first-order reactions.

By Roy Ernest Ballard

2 November 2014

This post is concerned with the kinetics of successive, irreversible, first order reactions. An earlier post on this subject  discussed the kinetics of a two-stage sequence. Here the complete solution is reported for the three-stage sequence:
The solution is:


For more details click the link below.


https://drive.google.com/file/d/0BxPw8lRke1HBUUVlT0RDT3RkQzA/view?usp=sharing





Sunday, September 28, 2014

Calculating matrix exponentials.
 I wanted to calculate by hand the exponential of a 3x3 matrix so I wrote out examples of two methods of doing this. To see the PDF click on the link below.

https://drive.google.com/file/d/0BxPw8lRke1HBQnd2RzFkNVYtQjA/view?usp=sharing




The kinetics of consecutive reactions.
This post presents the kinetic equation for consecutive chemical reactions of the type:

with irreversible, first order steps. They have rate constants k1 and k2 s-1. Let the concentrations of the reactants be expressed as xt,  yt,  zt  where xt  is the concentration of x at time t.
The kinetics of the sequence are completely determined by the equation:

 This solution was derived using Williamson’s algorithm as described below
https://drive.google.com/file/d/0BxPw8lRke1HBdmpfQ2hNMFFfVVU/view?usp=sharing.